They're not the same engines, I would assume the amount of boost plays a big role in how much blowby occurs (more blowby = the more crap to accumulate on the backs of the valves), and it's likely they're pushing more into each cylinder in the 2.5T than the
3.3TT [I don't know this to be the case, but it's typically how they get decent power from single turbo 4 cylinder engines].
Dumping chemicals into the engine directly while it's running isn't something to be taken lightly. I say/know this without having even heard of the cat issue, that only adds another potential complication to what is being sold in this thread as a fairly casual maintenance task.
I would never say "don't do it", but do so knowing the minimal potential risks.
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