Methanol toxicity is an acute phenomenon, ie the effects occur right away, not a long-term one. And methanol injection has been around for decades, yet we see no scourge of poisonings.
As
@AWDGT2 pointed out, your washer fluid is 1/3 methanol, so if a bumper tank leak is dangerous, then blasting jets of the stuff directly against the windshield would be doomsday.
A quick search yields studies using heating elements to actively vaporize methanol in enclosed spaces, to replicate industrial-scale exposure, while testing blood for buildup. I haven't attempted calculations of how much you'd have to dump into your trunk to match this, but we're not talking trace amounts.
So again, it's something to be careful with, but given the lack of poisoning incidents (and lawsuits against kit makers), it seems people are handling it ok.