We just added a 2.5 to our fleet. As with any cars/trucks, octane requirement depends on the prevailing vehicle and environmental conditions, as well as how you drive it. If you like to step hard on the loud pedal in 98F Summer heat, going up hill, with a car full of cargo/passenger, then for sure get the highest AKI pump gas you can find in your area. OTOH, if you are just taking it easy and hwy cruising all by yourself at 60mph in nice cool/cold weather, then regular unleaded works just fine with stock setup.
When I first got the car back in Sept, it was still brutally hot here in TX, so I filled up with mid-grade (89 in my area). Right now, the weather in my area has cooled off nicely, and since I prefer to hypermile for everyday commuting, I pump regular unleaded (87 in my area). That said, if I have an autoX or track even coming up, I would time my fill-up so that I'd have 93 in the tank for the event.
If modified, then follow the recommendation for the aftermarket device you installed.
As for launch control, 2.5T makes good torque but unfortunately does not have an LSD, so the open diff will be the limiting factor. At most all the software can do is to cut power to keep the wheel from breaking loose too badly. I just bought an LSD from a
G70 to swap into the 2.5T.