For North America, all 2.0T and 2.5T came with 18x8 wheels. I'm pretty sure 2.5T without the APEX package have larger brake rotors. There was a thread on this topic recently. My 2.5T has the APEX and Brembos, so I don't have first hand knowledge on that. However, OP has an '18 2.0T, so none of that applies.
Personally, I subscribe to the philosophy that a car can never have too much brakes. In fact, I value stopping power as much as - if not more than - HP. If I could upgrade to C8 Corvette 6-pot front and 4-pot rear at a reasonable price, I'd do it in a heartbeat. This is especially true for a heavy car like the Stinger. That said, a lot depends on your usage case. Not everybody will drive in ways that exposes the stock brake's weakness or take advantage of enhanced braking power. So, that's up to the individual driver to decide.
The only problem with the OEM Brembos on Stinger/
G70 is the OEM ceramic pads that most of them come with. Take that out of the system, and the Brembos perform excellently. Our '21
G70 6MT Sport came with factory Eurosport pads, which handled full-on track driving as well as both our Stingers' Brembos upgraded to EBC Bluestuff/Yellowstuff.
If the OP is wanting better brakes, the easiest way is to upgrade to more performance-oriented brake pad compound. For mostly street driving, EBC Yellowstuff has done well for me, but there are others like Hawk that are popular with enthusiasts. The downside is, of course, increased brake dust, which is almost always a accompanying effect of performance brake pads.
Changing from 320mm to 340mm might be a possibility, but that would likely require either a caliper mounting adapter, or different single-piston calipers. Highly unlikely that your current calipers would clear rotors that sit 10mm farther outward. IMO, getting that figured out is too much work. You might as well upgrade to Brembos at that point. Its a know quantity and opens you up for much more brake pad choices.