With only 91 octane at the pump, 4 gal E85 to 10 gal 91 is E31 / 95 octane (or: 1 gal E85 to 2.5 gal 91). Problem is - even if I can do this every time (a bit of a pain to ensure I get just the right mix, since I don't want to go OVER E31), my wife will NEVER go for it when she's driving. But, if I tell her "throw this 3oz bottle of gas enhancer into the tank first if you fill up", that's a lot easier to pull off.. I can even throw in the boostane at home to overload the existing tank, and it will more or less work if the drive isn't too far to the gas station. And, if you throw in a bit too much, oh well - octane is 96 or 97 or 98 for one tank, no big deal. No problems with exceeding E30 / fuel system capacity.
Until we can just fill up with E85 straight (which we do for her FF Pentastar), using something like boostane seems safer, even if more expensive.. No risk of OVER-doing it and starving the fuel system. And a bit less intrusive than WMI.