That would be a very odd choice. The secondary are far easier to change, and they have to come off when replacing the primaries anyway. Replacing the primaries already kills any hope of meeting smog controls and it's visually obvious, so no benefit there from keeping the secondaries.
So, sure, if you really want to, but the turbos won't react quite like the tune expects them to. There's also a chance the secondary cats will melt - they'll get a whole lot more fuel than they were ever designed to deal with.
It is physically possible to remove all the guts from a cat also. Just use caution - lots of heavy metals and interesting elements in there.